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Ukrainian President Volodymyr Zelensky accuses Russia of targeting civilian infrastructure, while Moscow reports that a warehouse was hit.
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Hundreds of homes and public buildings have been severely damaged with at least 53 people killed.
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Officials say flash flooding may have swept away homes with people in them in worst-hit areas.
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Dozens more are seriously injured after the tourist bus overturned in the early hours of Sunday morning.
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The 55.6-metre (182ft) concrete figure is head-and-shoulders above Rio de Jaineiro's Christ the Redeemer.